Bicyclo[10.2.0]tetradecan-13-one, fragrance use thereof, process

Perfume compositions – Perfume compositions – Ring containing active ingredient

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568374, 568304, A61K 746

Patent

active

050772740

ABSTRACT:
Described is the novel compound, bicyclo[10.2.0]tetradecan-13-one having the structure: ##STR1## as well as the use thereof in augmenting or enhancing the aroma of consumable materials including perfume compositions, colognes and perfumed articles (including solid or liquid anionic, cationic, nonionic or zwitterionic detergents, fabric softeners, cosmetic powders and hair preparations). Also described is a process for preparing said bicyclo[10.2.0]tetradecan-13-one using as a reaction intermediate the compound having the structure: ##STR2##

REFERENCES:
patent: 3465040 (1969-09-01), Nozaki et al.
patent: 3966819 (1976-06-01), Schulte-Elte et al.
patent: 4301303 (1981-11-01), Hoffman et al.
Danheiser et al., Tet Letters, vol. 28, pp. 3294-3302 (1987).
Mehta and Rao, "Ultrasound Promoted Dichloroketene-Olefin Cycloadditions", Synthetic Communications, 15(11), 991-1000, (1985).
Mehta dn Rao, "Strategy for Cyclopentenone Annulation of Olefins:A General Protocol for Bicyclo[n.3.0]Enone Synthesis", Tetrahedron Letters, vol. 25, No. 17, pp. 1839-1842, 1984.

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