Biaxially oriented LLDPE blends

Stock material or miscellaneous articles – Hollow or container type article – Shrinkable or shrunk

Reexamination Certificate

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C428S218000, C428S451000, C264S176100

Reexamination Certificate

active

08080294

ABSTRACT:
Disclosed in one aspect is a film comprising at least one core layer comprising a blend of at least 20 wt %, by weight of the core layer, of a first linear LLDPE having a molecular weight distribution (Mw/Mn) within the range of from 1.0 to 4.0; and at least 20 wt %, by weight of the core layer, of a second LLDPE—in a certain embodiment a short-chain branched LLDP—having a molecular weight distribution (Mw/Mn) within the range of from 1.0 to 7.0; characterized in that the density of the second LLDPE is greater than the density of the first LLDPE by at least 0.002 g/cm3; and/or the I2of the second LLDPE is greater than the I2of the first LLDPE by at least 0.5 dg/min. In certain embodiments, the first and second LLDPEs are produced by a metallocene-catalyzed reaction. In yet another embodiment, the combined molecular weight distribution (Mw/Mn) of the first and second LLDPEs is greater than 4.0.

REFERENCES:
patent: 5334428 (1994-08-01), Dobreski et al.
patent: 5376439 (1994-12-01), Hodgson et al.
patent: 6479138 (2002-11-01), Childress
patent: 6969741 (2005-11-01), Lustiger et al.
patent: 1 728 816 (2006-12-01), None
patent: WO2004/022634 (2004-03-01), None
patent: WO2004/031291 (2004-04-01), None
patent: WO2007/130277 (2007-11-01), None
D.M. Fiscus and P. Brandt in “Oriented Exceed™ Metallocene LLDPE Films, A New Option in Oriented Films” in Technical Association of Paper and Pulp Industry (TAPPI) Polymers, Laminations and Coatings Conference, Aug. 1998.
D.M. Fiscus and P. Brandt in “Film Property Enhancement by Orienting Metallocene LLDPE” in Schotland Conference, Houston, Texas Sep. 1997 and New Plastics '98 Conference in London, England, Jan. 1998.
Agustin Tones, Nelson Coils and Facundo Mendez in Properties Predictor for HDP/LDPE/LLDPE Blends for Shrink Film Applications in Journal of Plastic Film & Sheeting, vol. 22—Jan. 2006.
U.S. Appl. No. 11/726,806, filed Mar. 23, 2007, Inventor: Sid R. Wright, et al., entitled Films for Use in High Strength Bags.

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