Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing
Patent
1982-06-10
1984-05-08
Sebastian, Leland A.
Organic compounds -- part of the class 532-570 series
Organic compounds
Oxygen containing
568928, 568929, 568932, 568934, 568940, C07C 7910
Patent
active
044476620
ABSTRACT:
Aromatic hydrocarbons are nitrated by reacting the aromatic hydrocarbon in a nitrogen tetroxide-containing liquid reaction medium, in the presence of a beta-dicarbonyl compound having a "W" configuration with a carbonyl group at each apex of the "W", preferably at a pressure and temperature sufficient to maintain the nitrogen tetroxide in the liquid state. Addition of an inert organic co-solvent to the liquid nitrogen tetroxide for the metal acetylacetonate promoted nitration of benzene essentially eliminates the production of dinitrobenzenes.
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Johnson, Jr. Robert M.
Malhotra Ripudaman
Ross David S.
Air Products and Chemicals Inc.
Innis E. Eugene
Leach Michael
Sebastian Leland A.
Simmons James C.
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