.beta.-cyanoalkylsilane preparation using triorganophosphine com

Details .beta.-cyanoalkylsilane preparation using triorganophosphine com .beta.-cyanoalkylsilane preparation using triorganophosphine com

1993-11-23

1994-10-25

Shaver, Paul F.

Organic compounds -- part of the class 532-570 series

Organic compounds

Silicon containing

C07F 710

Patent

active

053591070

ABSTRACT:
A process for the preparation of hydrolyzable .beta.-cyanoalkylsilanes. More particularly, this invention relates to the catalytic addition of silicon hydrides to .alpha.,.beta.-unsaturated olefinic nitriles to form .beta.-cyanoalkylsilanes. The present invention uses an organic resin supported triorganophosphine, an organic resin supported triorganophosphine oxide, or triorganophosphine oxide as a catalyst.

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Ojima et al., J. Organomet. Chem. 111:43-60 (1976).
Capka et al., J. of Molecular Catalysis 11:313-322 (1981).
Capka et al., J. of Molecular Catalysis 11:323-330 (1981).

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