Compositions – Preservative agents – Anti-oxidants or chemical change inhibitants
Patent
1975-07-17
1977-07-26
Garvin, Patrick P.
Compositions
Preservative agents
Anti-oxidants or chemical change inhibitants
260 25AC, 260 75NC, 260 775AC, B01J 3102
Patent
active
040382109
ABSTRACT:
Cellular urethane polymers essentially free of the strong, objectionable amine odor characteristic of N-ethylmorpholine, are provided by effecting the polyurethane forming reaction in the presence of beta-tertamino nitriles. In view of their low residual odor and effectiveness in the catalysis of the water-isocyanate reaction, the beta-amino nitriles either alone or in combination with other tertiary amines, are used with particular advantage as direct replacements for N-ethylmorpholine in the manufacture of water-blown flexible polyurethanes, both molded and free-rise, including high-resilience foam as well as foams stabilized with either organosilicone or silicon-free organic surfactants. Especially effective for the formation of flexible polyester foam stabilized with either type of surfactant are blends of the beta-amino nitrile catalyst such as, in particular, 3-(N,N-dimethylamino)propionitrile, with dimethylethanolamine or a bis[2-(N,N-dimethylamino)alkyl]-ether.
REFERENCES:
patent: 3821131 (1974-06-01), Priest et al.
patent: 3836488 (1974-09-01), Pruitt et al.
Rosemund Walter Richard
Sandner Michael Ray
Trecker David John
Garvin Patrick P.
Klosty Marylin
Union Carbide Corporation
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