Chemistry: electrical current producing apparatus – product – and – Current producing cell – elements – subcombinations and... – Include electrolyte chemically specified and method
Patent
1996-09-03
1997-11-25
Skapars, Anthony
Chemistry: electrical current producing apparatus, product, and
Current producing cell, elements, subcombinations and...
Include electrolyte chemically specified and method
423119, 423600, 501120, 501153, H01M 618, C01F 700
Patent
active
056910827
ABSTRACT:
A beta-alumina solid electrolyte for use in a sodium-sulfur battery is composed of beta-alumina crystals having a degree of orientation toward the C axis thereof, of 0.2-0.4 and an aspect ratio of 4.0 or less. The beta-alumina solid electrolyte is composed of the beta-alumina crystals having a degree of orientation toward the C axis thereof, of 0.2-0.4 and has such a particle diameter distribution that the average particle diameter is 3 .mu.m or less, the proportion of the particles having a particle diameter of 5 .mu.m or less is 90% or more, and the maximum particle diameter is 300 .mu.m or less. A process for producing a beta-alumina solid electrolyte using an alumina source material, a magnesium source material and a sodium source material, uses a magnesium-aluminum spinel as the magnesium source material and subjects all materials to mixing, granulation, molding and firing to obtain a beta-alumina solid electrolyte without subjecting the materials to calcination. The beta-alumina solid electrolyte has a low electrical resistance and a large strength to internal water pressure and exhibits excellent properties when used as a diaphragm for a sodium-sulfur battery.
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Kajihara Takehiro
Kajita Masaharu
Totoki Takao
NGK Insulators Ltd.
Skapars Anthony
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