Benzylic oxidation process

Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing

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252469, 252470, 252467, 252468, C07C 4536

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active

042436125

ABSTRACT:
A vapor phase process for the direct oxidation of a methyl benzene to the corresponding aldehyde derivative; e.g., conversion of toluene to benzaldehyde, wherein said oxidation is effected in the presence of a catalyst system consisting essentially of uranium and molybdenum oxides in combination with an oxide of lead, tin, zirconium, cadmium, antimony or nickel.

REFERENCES:
patent: 3579589 (1971-05-01), Delman
patent: 3714263 (1973-01-01), Cyba
patent: 3859358 (1975-01-01), Grasselli et al.
patent: 3933751 (1976-01-01), Callahan et al.
Ai et al., Chem. Abst., vol. 77, #66559k (1977).

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