Benzylic ether phenolic resole resins and their uses

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – From phenol – phenol ether – or inorganic phenolate

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Details

523143, 523145, 524372, 524375, 525504, 528154, 528243, 528493, 528495, 528502C, 528503, 26433119, C08G 804, C08G 1402

Patent

active

059089148

ABSTRACT:
This invention relates to benzylic ether phenolic resole resins prepared in a sealed reaction vessel and their uses. The benzylic ether phenolic resole resins are prepared by heating phenol and an aldehyde in a sealed reaction vessel in the presence of a divalent metal catalyst without removing water generated by the reaction until an appropriate endpoint for the resin is reached. The benzylic ether phenolic resole resins produced by the process are preferably free or essentially free of unreacted formaldehyde and can be used in the resin component of phenolic-urethane foundry binders to make foundry cores and/or molds by the cold-box and no-bake processes. The cores and/or molds are used for making metal castings.

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R. W. Martin in The Chemistry of Phenolic Resole Resins, John Wiley & Sons, 1956, p. 111.
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Ashland Internal Report entitled Characterization of Two-Part Foundry Binder System: Deltacure 124-156 (Part I) and Deltacure 23-15 (Part II) dated Sep. 15, 1995.
Ashland Internal Report entitled Characterization of Three Part No Bake Binder System: Delta Techniset 20-463(I), Techniset 23-414 (II) and Techniset 17-727 (III) dated Oct. 5, 1995.

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