Benzyl and aryl esters of N-phosphonomethyl glycines, herbicidal

Chemistry: fertilizers – Processes and products – Forms or conditioning

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71 87, 260944, A01N 936, C07F 909

Patent

active

041206894

ABSTRACT:
Alkyl-[di(benzyl) or di(aryl)]esters of N-phosphonomethyl glycine are produced by the reaction of a dibenzyl or diaryl phosphite with an N-methylene alkyl glycinate trimer. These esters and the hydrolysis products thereof containing at least one benzyloxy or aryloxy group bonded to phosphorus are novel compounds having the formula ##STR1## wherein R is a member of the group consisting of phenyl, benzyl, naphthyl, biphenylyl, benzyloxyphenyl and phenyl, benzyl or naphthyl groups substituted with from 1 to 3 groups selected from the class consisting of hydroxyl, lower alkyl, lower alkoxy, lower alkylthio, trifluoromethyl, carbo (lower alkoxy), nitro, or halo; R.sub.1 is hydrogen or an R group, and R.sub.2 is a lower alkyl group or hydrogen, and the strong acid salts of the compounds wherein neither R.sub.1 or R.sub.2 is H. These compounds are useful as post-emergent herbicides.

REFERENCES:
patent: 3799758 (1974-03-01), Franz
patent: 3859183 (1975-01-01), Wagenknecht

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