Benzothiepine 1, 1-dioxide derivatives, a process for their...

Drug – bio-affecting and body treating compositions – Designated organic active ingredient containing – Having -c- – wherein x is chalcogen – bonded directly to...

Reexamination Certificate

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Reexamination Certificate

active

07019023

ABSTRACT:
Substituted benzothiepine 1,1-dioxide derivatives of formula I:in which R1, R2, R3, R4, R5and Z have the meanings indicated, and their physiologically tolerable salts and physiologically functional derivatives and a process for their preparation are described. The compounds are suitable, for example, as hypolipidemics.

REFERENCES:
patent: 3287370 (1966-11-01), Mohrbacher et al.
patent: 3389144 (1968-06-01), Mohrbacher et al.
patent: 3520891 (1970-07-01), Mohrbacher et al.
patent: 3694446 (1972-09-01), Houlihan et al.
patent: 3758528 (1973-09-01), Malen et al.
patent: 3770728 (1973-11-01), Bourquin et al.
patent: 3821249 (1974-06-01), Malen et al.
patent: 3853915 (1974-12-01), Bourquin et al.
patent: 3928383 (1975-12-01), Kaplan et al.
patent: 3954764 (1976-05-01), Gerecke et al.
patent: 4044010 (1977-08-01), Gerecke et al.
patent: 4045570 (1977-08-01), Dörhöfer et al.
patent: 4153612 (1979-05-01), McCall
patent: 4185109 (1980-01-01), Rosen
patent: 4207239 (1980-06-01), McCall
patent: 4237296 (1980-12-01), Gadient
patent: 4247553 (1981-01-01), McCall
patent: 4251526 (1981-02-01), McCall
patent: 4436749 (1984-03-01), Hatinguais et al.
patent: 5037825 (1991-08-01), Klaus et al.
patent: 5158943 (1992-10-01), Sohda et al.
patent: 5164387 (1992-11-01), Klaus et al.
patent: 5169857 (1992-12-01), Angerbauer et al.
patent: 5300522 (1994-04-01), Klaus et al.
patent: 5420273 (1995-05-01), Klaus et al.
patent: 5430116 (1995-07-01), Kramer et al.
patent: 5491152 (1996-02-01), Wilde et al.
patent: 5547975 (1996-08-01), Talley et al.
patent: 5594001 (1997-01-01), Teleha et al.
patent: 5602152 (1997-02-01), Berthelone et al.
patent: 5652252 (1997-07-01), Berthelone et al.
patent: 5670532 (1997-09-01), Talley et al.
patent: 5886016 (1999-03-01), Talley et al.
patent: 5994391 (1999-11-01), Lee et al.
patent: 5998400 (1999-12-01), Brieaddy et al.
patent: 6013809 (2000-01-01), Zimmer et al.
patent: 6083977 (2000-07-01), Boehm et al.
patent: 6107494 (2000-08-01), Lee et al.
patent: 6143755 (2000-11-01), Bocan
patent: 6180660 (2001-01-01), Whitney et al.
patent: 6221897 (2001-04-01), Frick et al.
patent: 6235771 (2001-05-01), Shiraishi et al.
patent: 6262277 (2001-07-01), Lee et al.
patent: 6268392 (2001-07-01), Keller et al.
patent: 6277831 (2001-08-01), Frick et al.
patent: 6369220 (2002-04-01), Li et al.
patent: 6387924 (2002-05-01), Lee et al.
patent: 6387944 (2002-05-01), Frick et al.
patent: 6420417 (2002-07-01), Keller et al.
patent: 6441022 (2002-08-01), Frick et al.
patent: 2002/0032329 (2002-03-01), Babiak et al.
patent: 2002/0061888 (2002-05-01), Keller et al.
patent: 2003/0017996 (2003-01-01), Frick et al.
patent: 2011806 (1970-10-01), None
patent: 0067086 (1982-12-01), None
patent: 0250265 (1987-12-01), None
patent: 0350846 (1990-01-01), None
patent: 0508425 (1992-10-01), None
patent: 0781278 (1997-07-01), None
patent: 0791592 (1997-08-01), None
patent: 0922703 (1999-06-01), None
patent: 2661676 (1991-11-01), None
patent: 2698873 (1994-06-01), None
patent: 1211258 (1970-11-01), None
patent: 1428110 (1976-03-01), None
patent: 506297 (1976-03-01), None
patent: 550982 (1977-03-01), None
patent: 591146 (1978-01-01), None
patent: WO 93/16055 (1993-08-01), None
patent: WO 96/08484 (1996-03-01), None
patent: WO 96/16051 (1996-05-01), None
patent: WO 97/33882 (1997-09-01), None
patent: WO 98/38182 (1998-09-01), None
patent: WO 98/40375 (1998-09-01), None
patent: WO 98/55118 (1998-12-01), None
patent: WO 99/32478 (1999-07-01), None
patent: WO 00/01687 (2000-01-01), None
patent: WO 00/38725 (2000-07-01), None
patent: WO 01/68637 (2001-09-01), None
patent: WO 02/08211 (2002-01-01), None
Ali, M., et al., “Reactions with 2,3,4,5-Tetrahydro-benzo (B) Thiepin-5-One and Its Derivatives,”J. Prakt. Chem.316(2):259-266(1974).
Almena J. et al, “Reductive Opening of Thiophthalan: A New Route to Functionalised Sulfur-Containing Compounds.”, J. Org. Chem., vol. 61, pp. 1859-1862, 1996.
Baumgarth M. et al, “Bicyclic Acylguanidine Na+/H+Antiporte Inhibitors”, J. Med. Chem. vol. 41, pp. 3736-3747, 1998.
Bentley, K. W. et al., “Pharmaceutical Antihypertensive and Vasodilator Compositions”, Chemical Abstracts, vol. 85, p. 516, (1976).
Berthelon et al., “Benzoxepinopyridine derivatives,” Chemical Abstracts, vol. 121, p. 1161 (1994).
Bohme, H. and Haack, B., “[Derivatives of 1,3,4,5-tetrahydro-2-benzothiepin with a basic side chain in the 1-position],”Arch. Pharm. Ber. Dtsch. Pharm. Ges.302(1):72-74 (1969).
Braun et al. “2,3,4,5,6-Penta-O-Acetyl-D-Gluconic Acid and 2,3,4,5,6-Penta-O-Acetyl-D-Gluconyl Chloride,” Organic Synthesis, vol. 5, pp. 887-891 (1973).
Chatterjee, A., et al., “Ring contraction of some 1-benzothiepin derivatives to 1-benzothiophens,”J. Chem. Soc. Perkin Trans.1:1707-1711 (1981).
Corelli F. et al., “Diltiazem-like Calcium Entry Blockers: A Hypothesis of the Receptor-Binding Site Based on a Comparative Molecular Field Analysis Model.”, J. Med. Chem., vol. 40, pp. 125-131, 1997.
Deshayes C. et al. “Synthesis of some 4-Acetyl-3,5-dioxo-2,3,4-tetrahydro[1]benzoxepine or Benzothiepine and 6-Acetyl-5,7-dioxo-6,7,8,9-tetrahydor-5H-benzocycloheptene Derivatives”, J. Heterocyclic Chem., vol. 22, No. 6, pp. 1659-1662, (1985).
Ferrari, R., et al., “How do calcium antagonists differ in clinical practice?,”Cardiovascular drugs and therapy8:565-575 (1994).
Hofmann, H. and Dickert, F., “The dynamic behaviour of the 1-methyl-1-benzothiepinium ring system,” Z.Natuforsch. B Anorg. Chem. Org. Chem.36(8):974-977 (1981).
Hofmann, H. and Djafari, H., “Heterocyclic seven-membered ring compounds, xxxiv. A simple synthesis of 1-benzoxepine and 1-benzothiepine,”Z. Natuforsch. B44(2):220-224 (1989).
Hofmann, H. and Djafari, H., “Heterocyclic seven-membered ring compounds, xxviii.—on 5-acetoxy-and 5-methoxy-1-benzothiepine and analogous 1-benzoxepines,”Liebigs Ann. Chem.3:599-604 (1985).
Hofmann, H. and Djafari, H., “Heterocyclic seven-membered ring compounds, xxxi.—the photochemical behaviour of monosubstituted 1-benzothiepines,”Liebigs Ann. Chem.505-508 (1987).
Hofmann, H. and Heidrich, R., “Heterocyclic seven-membered ring compounds, xxiv. Photochemical reaction of 2-methyl-4-phenyl-1-benzothiepins,”Z. Naturforsch. B. Anorg. Chem. Org. Chem.37(10):1344-1345 (1982).
Hofmann, H. and Heidrich, R., “Heterocyclic Seven-Membered Ring Compounds XXIII. Synthesis and Thermolytic Behavior of 2-Methyl-4-Phenyl-1-benzothiepins”Z. Naturforsch. B34(8):1145-1148 (1979).
Hofmann, H. and Loew, G., “Heterocyclic seven-membered ring compounds, xxvii. Synthesis and thermal reactivity of 1,2-dimethyl-4-phenyl-1-benzothiepinium salts,”Z. Naturforsch. B Anorg. Chem. Org. Chem.39(7):985-989 (1984)
Hofmann, H., et al., “Heterocyclic seven-membered ring compounds, xxv—synthesis and thermolysis of substituted 1-methyl-4-phenyl-1-benzothiepinium salts,”Liebigs Ann. Chem.3:425-432 (1983).
Hofmann, H., et al., “Synthesis of stable 1-benzothiepins,”Angew Chem. Int. Ed. Engl.11(5): 423-424 (1972).
Huckle et al., “4-Amino-2,3,4,5-tetrahydro-1-benzoxepin-5-ols , 4-Amino-2,3,4,5-tetrahydro-1-benzothiepin-5-ols and related compounds,”J. Chem. Soc. C12:2252-2260 (1971).
Ishino Y. et al., “Novel Synthesis of 4,5-Bis(arylthio)-2,3,4,5-tetrahydro-1-benzothiepins: Noteworthy Cyclization by the Reaction of 2-Butynedion with Arenethiols in the Presence of Zinc Iodide.”, Communications, pp. 827-829, 1987.
Jilek J. et al., “8-Chloro and 8-Methylthio Derivatives of 10-Piperazino-10,11-DiHydrodisenzo[b,f]Thiepins; New Compounds and New Procedures”, Neurotropic and Psychotropic Agents: Part CLXXVII, Journal 48, pp. 906-927, (1983).
Journal Bioorganicheskaya khimiya, (Bioorganic chemistry), Publisher Nauka, Academy of Sciences of the USSR, v. 9, No 10, 1983, pp. 1357-1358 and partial translation.
Journal of organic chemi

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