Benzophenone hydrazone derivatives as insecticides

Drug – bio-affecting and body treating compositions – Designated organic active ingredient containing – N-c doai

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514 63, 514487, 514512, 514513, 514514, 514521, 514523, 514590, 514615, 514639, 556413, 556420, 558 15, 558247, 558257, 558391, 558396, 558397, 560 9, 560 13, A01N 4712, C07C32348

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060778660

ABSTRACT:
Novel benzophenonehydrazone derivatives represented by the formula (I): ##STR1## wherein, R.sup.1 is halogen; R.sup.2 is hydrogen or C.sub.1-4 alkyl; R.sup.3 is cyano, optically substituted C.sub.1-4 alkyl, C.sub.2-4 alkenyl, C.sub.3-4 alkynyl, C.sub.1-4 alkyl-carbonyl or C.sub.1-4 alkoxy-thiocarbonyl; R.sup.4 is hydrogen, phenyl, optionally substituted C.sub.1-6 alkyl, optionally substituted C.sub.2-8 alkenyl, --CO--R.sup.8, --CO--O--R.sup.9 or ##STR2## R.sup.5 is hydrogen, formyl, phenyl, optionally substituted C.sub.1-8 alkyl, optionally substituted C.sub.2-8 alkenyl, optionally substituted C.sub.3-8 alkynyl, optionally substituted C.sub.1-8 alkyl-arbonyl, optionally substituted C.sub.1-6 alkyl-oxalyl, optionally substituted C.sub.1-8 alkoxy-carbonyl, optionally substituted C.sub.1-8 alkoxy-oxalyl, optionally substituted C.sub.3-8 cycloalkyl-carbonyl, optionally substituted C.sub.2-8 alkenyl-carbonyl or optionally substituted benzoyl; R.sup.6 is hydrogen or halogen; R.sup.7 is hydrogen, halogen or C.sub.1-2 alkyl, C.sub.1-4 alkyl-carbonyl or C.sub.1-4 alkoxy-thiocarbonyl; n is 0, 1 or 2, provided that n is 0 when R.sup.3 is cyano, C.sub.1-4 alkyl-carbonyl or C.sub.1-4 alkoxy-thiocarbonyl, is a single bond of Anti form or of Syn form.
The benzophenonehydrazone derivatives of the formula (I) have excellent insecticidal activities.

REFERENCES:
patent: 4331680 (1982-05-01), Giles et al.
patent: 4344893 (1982-08-01), Copping et al.
patent: 4394387 (1983-07-01), Copping et al.
patent: 4432994 (1984-02-01), Giles et al.
patent: 4980373 (1990-12-01), Kisida et al.
patent: 5728699 (1998-03-01), Toriyabe et al.
Abstract of JP 03074356 A; "New hydrazone compounds . . . "; Sumitomo Chem.Ind.KK; Aug. 10, 1989.
Abstract of JP 04001173 A; "Agent for exterminating . . . "; Chugai Pharmaceutical KK; Apr. 17, 1990.
Abstract of AU 9510291 A; "Benzophenone acyl;hydrozone(s) . . . "; Sumitomo Chem.Co.Ltd.; Jan. 24, 1994.

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