Benzimidazole-2-carboxanilides

Details Benzimidazole-2-carboxanilides Benzimidazole-2-carboxanilides

1989-08-11

1991-01-01

Ramsuer, Robert W.

Organic compounds -- part of the class 532-570 series

Organic compounds

Heterocyclic carbon compounds containing a hetero ring...

544139, 544370, 546199, 548331, C07D23524, C07D40512, C07D41306

Patent

active

049819755

ABSTRACT:
Benzimidazolecarboxanilides of the formula (I) ##STR1## where R.sup.1 and R.sup.2 are each H, Cl, alkyl, alkoxy, unsubstitued or alkyl- or alkoxy-substituted phenyl or phenylalkyl, R.sup.3 and R.sup.4 are each H, uninterrupted or --O-- interrupted alkyl or alkoxy, unsubstituted or alkyl- or alkoxy-substituted phenyl, phenylalkyl, phenoxy, phenylalkoxy hydroxyalkyl, hydroxyalkoxy, alkylcarbonylamino, alkanoyloxy, benzoylamino or benzoyloxy, X is alkylene, n is 1 or 2 and where--if n is 1--R.sup.5 is Cl, --OR.sup.6 or --NR.sup.7 R.sup.8 or--if n is 2--R.sup.5 is --O--R.sup.12 --O-- or --N(R.sup.9)--R.sup.13 --N(R.sup.9)-- where R.sup.6 is H, unsubstituted, OH-- or alkanoyloxy-substituted alkyl whose carbon chain may be interrupted by --O-- or --N(R.sup.9)--, cycloalkyl, alkenyl, phenylalkyl, phenoxyethyl, hydroxy alkyl, phenylhydroxyalkyl or glycidyl, R.sup.7 and R.sup.8 are H, alkyl, cycloalkyl, phenyl, naphthyl, alkenyl, phenylalkyl, hydroxyalkyl or --NR.sup.7 R.sup.8, a saturated 5- or 6- membered heterocycle, R.sup.9 is alkyl, cycloalkyl, alkenyl, phenyl, naphthyl or phenylalkyl, R.sup.12 is alkylene, alkenylene, cyclohexylene, oxaalkylene and R.sup.13 is alkylene, oxaalkylene, diphenylenemethane or dicyclohexylenemethane or --N(R.sup.9)--R.sup.13 --N(R.sup.9)-- is piperazinylene, are excellent light stabilizers for organic materials such as polymers and coating binders.

REFERENCES:
patent: 3661925 (1972-05-01), McCaully et al.
patent: 3740413 (1973-06-01), McCaully et al.
patent: 3907700 (1975-09-01), Grier
patent: 4011236 (1977-03-01), Grier
patent: 4820757 (1989-04-01), Spang et al.

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