Benzene-1,3,5-tris-acetoxime and the process for making phlorogl

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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C07C13100

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041154517

ABSTRACT:
Phloroglucinol may be produced by converting s-triacetyl benzene to benzene-1,3,5-tris-acetoxime which is a novel compound. Said acetoxime is subjected to a Beckmann rearrangement and the resulting mixture subsequently hydrolyzed to produce phloroglucinol.

REFERENCES:
chemical Abstracts, vol. 72, column 132,312z (U.S.S.R. 254,516) (1970).
Organic Reactions, vol. 11 (Adams et al) pp. 55-56.

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