Bathophenanthroline compound and EL device

Stock material or miscellaneous articles – Composite – Of inorganic material

Reexamination Certificate

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C428S917000, C313S504000, C313S506000, C257SE51050

Reexamination Certificate

active

10798820

ABSTRACT:
A novel bathophenanthroline compound of the general formula [I] or [II] is providedwherein R1and R2may be the same or different and independently represent a linear, branched or cyclic, saturated or unsaturated hydrocarbon group, or a substituted or unsubstituted, saturated or unsaturated hydrocarbon group provided that at least one of R1and R2has at least two carbon atoms, and wherein Ar1and Ar2may be the same or different and independently represent a substituted or unsubstituted aryl group. A process for preparing the compound is also provided wherein bathophenanthroline and an organolithium compound are subjected to nucleophilic substitution reaction to obtain the compound of the above formula [I] or [II].

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patent: 6524728 (2003-02-01), Kijima et al.
patent: 0564224 (1993-10-01), None
patent: WO99/53724 (1999-10-01), None
Sugihara, H. et al.; “Lithium lon-Selective Electrodes Based on 1,10-Phenanthroline Derivatives,”Analytical Sciences, Oct. 1993, vol. 9, pp. 593-597.
Case, F. et al. “Substituted 1, 10-Phenanthrolines, VIII. 2-and 3-Phenyl Derivatives,”Journal of Organic chemistry, Oct. 1955, vol. 20, pp. 1330-1336.
Dietrich-Buchecker, C.O., “Direct Synthesis of Disubstituted Aromatic Polyimine Chelates,” Tetrahedron Letters, 1982, vol. 23 No. 50, pp. 5291-5294.
Dietrich-Buchecker, C.O., “Interlocked Macrocyclic Ligands: A Catenand Whose Rotation of One Ring Into The Other is Precluded By Bulky Substituents,” Tetrahedron Letters, 1986, vol. 27, No. 20, pp. 2257-2260.

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