Basic metal salts of sulfur- and methylene-bridged poly-phenol c

Details Basic metal salts of sulfur- and methylene-bridged poly-phenol c Basic metal salts of sulfur- and methylene-bridged poly-phenol c

1975-09-04

1977-05-03

Phillips, Delbert R.

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

260125, 260609F, 252 427, 260137, C07G 1700

Patent

active

040214192

ABSTRACT:
Novel polyphenol compositions are prepared by successively reacting a phenol with formaldehyde or a reversible polymer thereof and sulfurizing the same with sulfur or a sulfur halide. The formaldehyde reaction and sulfurization may be effected in either order, but preferably the formaldehyde reaction takes place first. The resulting polyphenols are useful as oxidation inhibitors in lubricants. They may also be reacted with epoxides, and either the polyphenols or the epoxide reaction products thereof may be reacted with metal bases (especially alkali metal and alkaline earth metal bases, and preferably barium or calcium) to yield basic salts. The basic salts may also be reacted with epoxides, preferably ethylene oxide and propylene oxide. The basic salts thus obtained are useful in lubricants as detergents and oxidation inhibitors.

REFERENCES:
patent: 2451037 (1948-10-01), McCleary et al.
patent: 2472517 (1949-06-01), Cantrell et al.
patent: 2472518 (1949-06-01), Cantrell et al.
patent: 2472552 (1949-06-01), Smith et al.
patent: 2629743 (1953-02-01), Burnette et al.
patent: 3035908 (1962-05-01), Gottshall et al.
patent: 3498936 (1970-03-01), Wilson
patent: 3883501 (1975-05-01), Malec et al.
patent: 3903173 (1975-09-01), Eggensperger et al.

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