Azo pyrazolone pigments

Details Azo pyrazolone pigments Azo pyrazolone pigments

1997-07-17

1999-07-06

Higel, Floyd D.

Organic compounds -- part of the class 532-570 series

Organic compounds

Azo

534728, 106402, 106496, C09B 6300, C09B 2948, C09B 2950, C09B 6904, C08R 542

Patent

active

059199156

DESCRIPTION:

BRIEF SUMMARY
This invention relates to monoazo pigments and more particularly to greenish-yellow pigments of the azo pyrazolone series.
The use of pigments for the colouring of plastics materials is well known. For the production of yellow colorations, it has been traditional to employ inorganic pigments such as cadmiums and lead chromes but these are now being phased out because of environmental pressures.
Organic pigments that have been proposed as replacements for these inorganic materials include compounds of the formula: ##STR2## wherein X is Cl (DE-OS 2616981) or CH.sub.3 (U.S. Pat. No. 5,047,517).
Other yellow pigments, described in DE-OS 3318073, include compounds of the formula: ##STR3## wherein X is again Cl or CH.sub.3.
The above mentioned organic pigments are generally suitable for the production of reddish-yellow colorations but it has now been found that greenish-yellow shades having superior light stability, together with excellent heat stability and bleed fastness can be obtained from the compounds hereinafter defined.
Accordingly, the invention provides an azo pyrazolone compound of the formula: ##STR4## wherein Z represents a substituent selected from Cl, Br, F, NO.sub.2, SO.sub.2 R, CO.sub.2 R, NHSO.sub.2 R.sup.1 and NHCOR.sup.1 in which R and R.sup.1 are hydrocarbyl and the sulphonic acid group of ring A is in the 3- or 4-position relative to the pyrazolyl group, said compound being in the form of a salt.
The salt of the azo pyrazolone compound of Formula 1 may be a metal salt, for example an alkali metal, alkaline earth metal or heavy metal salt, or a salt of a nitrogenous base, for example a primary, secondary or tertiary amine or quaternary ammonium salt, particularly useful pigments being the salts of barium, strontium, manganese, magnesium, sodium and, especially, calcium.
Preferred compounds of the invention have the formula: ##STR5## wherein Z is as defined above, R preferably being an alkyl, for example C.sub.1-6 -alkyl, group and R.sup.1 preferably being an aryl, for example phenyl or tolyl, group.
The azo pyrazolone compounds of the invention may be prepared by diazotising a substituted sulphonated aniline of the formula: ##STR6## wherein Z is as defined above and coupling the resulting diazo compound with a sulphonated 3-methyl-1-phenylpyrazol-5-one of the formula: ##STR7## wherein the sulphonic acid group is in the 3- or 4-position relative to the pyrazolyl group, and converting the resulting monoazo compound to the desired salt form.
The diazotisation and coupling reactions may be performed in a conventional manner appropriate to the classes of compound being used.
The preferred substituted sulphonated aniline for use in preparing the compounds of the invention is 2-amino-4-chlorobenzene sulphonic acid whilst the preferred coupling component is 3-methyl-1-(3'-sulphophenyl)pyrazol-5-one.
It is often convenient to prepare the compound of Formula 1 in the form of a sodium salt and then to convert the sodium salt to, for example, an alkaline earth or heavy metal lake by adding the required amount of a water-soluble alkaline earth or heavy metal salt, usually in the form of an aqueous solution.
Surface active agents and/or organic solvents may optionally be present during the synthesis of the compound of Formula 1 and/or during precipitation of the pigment.
The compounds of the invention, which may be subjected to conventional milling operations and/or thermal treatments in order to provide products of the desired particle size and/or crystal structure, are useful yellow pigments which may be used in conventional manner. In particular, they may be used alone or in conjunction with other pigments for the coloration of plastics materials, for example polyvinyl chloride, polyolefins, polystyrene and ABS where they exhibit excellent properties. The compounds of the invention are also valuable for the pigmentation of surface coatings.
The invention is illustrated but not limited by the following Examples.


EXAMPLE 1

2-Amino-4-chlorobenzene sulphonic acid (4.15 g), deionised water (50 ml) and hy

REFERENCES:
patent: 1731150 (1929-10-01), Reber et al.
patent: 4594411 (1986-06-01), Henning
patent: 4992495 (1991-02-01), Hari et al.
patent: 5047517 (1991-09-01), Deucker
patent: 5457188 (1995-10-01), Zimmermann I

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