Aziridine complexes isomerize to form chelated dimers

Details Aziridine complexes isomerize to form chelated dimers Aziridine complexes isomerize to form chelated dimers

1973-05-09

1979-10-09

Berch, Mark L.

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

71 88, C07D20312, A01N 922

Patent

active

041705912

ABSTRACT:
Metal salt complexes of aziridine and 2-alkylaziridines in solution isomerize at temperatures between 20.degree.-70.degree. C. to form aziridine dimer chelates. The chelates are biologically active compounds and are chemical intermediates in the preparation of free aziridine dimers.

REFERENCES:
root et al., A.C.S. Abs. of Papers, 156th Meeting (1968), Abstract INOR 145.
Jackson et al., J.A.C.S. 83, 355-360 (1961).
Jackson et al., Inorg. Chem. 1, 398-401 (1962).
Kiser et al., Inorg. Chem. 1, 401-404 (1968).
Patai, "The Chemistry of the Hydroxyl Groups" (Interscience Publishers, 1971), p. 369.
Takemoto et al., Chem. Abs. 72, 83379r (1970).
Cotton et al., Advanced Inorg. Chem., 2nd Ed. Interscience Publishers, p. 826.

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