Azeotropic fumigant compositions of methyl iodide

Compositions – Vaporization – or expansion – refrigeration or heat or energy...

Reexamination Certificate

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C252S068000, C252S069000, C510S177000, C510S408000, C510S412000, C510S415000, C424S405000, C514S743000, C514S744000, C514S746000

Reexamination Certificate

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07544306

ABSTRACT:
Azeotropic and azeotrope-like compositions of methyl iodide and at least one fluorocarbon or hydrofluorocarbon such as 1,1,1,3,3-pentafluoropropane (HFC-245fa). The compositions are present as a gas, at temperatures of about 30° C. or below. The inventive compositions serve as a non-ozone-depleting gaseous fumigant which is useful in a variety of applications, in place of methyl bromide. These compositions serve as a drop-in replacement for gaseous methyl bromide, providing the benefits of a methyl iodide fumigant while also utilizing existing methyl bromide equipment.

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“Dose Response of Weeds To Methyl Iodide and Methyl Bromide.” W.M. Zhang, et al., Weed Research, 1997, vol. 37, 181-189.
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“Methyl Iodide, an Ozone-Safe Alternative To Methyl Bromide As a Soil Fumigant.” H.D. Ohr, et al., Plant Disease 80: 731-735. Jul. 1996.
“Methyl Iodide: An Alternative To Methyl Bromide For Insectary Fumigation.” M. Waggoner, et al., J. Appl. Ent. 124, , 113-117 (2000).

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