Automatic dishwashing compositions comprising cobalt catalysts

Details Automatic dishwashing compositions comprising cobalt catalysts Automatic dishwashing compositions comprising cobalt catalysts

1997-02-06

1998-01-06

Lieberman, Paul

Cleaning compositions for solid surfaces, auxiliary compositions

Cleaning compositions or processes of preparing

For cleaning a specific substrate or removing a specific...

134252, 510220, 510221, 510224, 510226, 510372, 510374, 510376, 502125, 502127, 556148, 556149, C11D 339, C11D 3395, C11D 754, B08B 304

Patent

active

057054649

ABSTRACT:
Automatic dishwashing detergent compositions comprising certain cobalt catalysts are provided. More specifically, the invention relates to automatic dishwashing detergents which provide enhanced cleaning/bleaching benefits (especially tea stain removal) through the selection of cobalt bleach catalyst having the formula:
wherein cobalt is in the +3 oxidation state; n is 4 or 5 (preferably 5); M is one or more ligands coordinated to the cobalt by one site; m is 0, 1 or 2 (preferably 1); B is a ligand coordinated to the cobalt by two sites; b is 0 or 1 (preferably 0), and when b=0, then m+n=6, and when b=l, then m=0 and n=4; and T is one or more appropriately selected counteranions present in a number y, where y is an integer to obtain a charge-balanced salt (preferably y is 1 to 3; most preferably 2 when T is a -1 charged anion); and wherein further said catalyst has a base hydrolysis rate constant of less than 0.23 M.sup.-1 s.sup.-1 (25.degree. C.).
Preferred automatic dishwashing compositions comprise amylase and/or protease enzymes. Included are methods for washing tableware in domestic automatic dishwashing appliances using the cobalt catalysts.

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