Autoclave soda digestion of scheelite concentrates

Chemistry of inorganic compounds – Treating mixture to obtain metal containing compound – Group vib metal

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423 53, 423 58, C01G 4100

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active

043518087

ABSTRACT:
A process for the soda ash digestion of scheelite concentrates is provided, the process comprising forming a slurry of a scheelite concentrate in an aqueous sodium carbonate solution and then digesting the slurry in an autoclave at an elevated temperature of at least about 180.degree. C. The concentration of the Na.sub.2 CO.sub.3 solution is substantially inversely correlated to the digestion temperature and substantially directly correlated to the Na.sub.2 CO.sub.3 /WO.sub.3 weight ratio such as to effect the selective dissolution of at least about 95% of the WO.sub.3 in the concentrate and provide a pregnant liquor containing WO.sub.3 while inhibiting substantial dissolution of gangue minerals.

REFERENCES:
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patent: 4092400 (1978-05-01), Zbranek et al.
patent: 4167555 (1979-09-01), Gomes et al.
Grigoriu et al., "Chemical Absts.", vol. 61, 1964, #9209a.
Nasu, "Chemical Absts.", vol. 61, 1964, #5251a.
Zelikman et al., "Chemical Absts.", vol. 89, 1978, #133090p.

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