Auto exhaust catalyst composition having low H.sub.2 S emissions

Catalyst – solid sorbent – or support therefor: product or process – Catalyst or precursor therefor – Metal – metal oxide or metal hydroxide

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502207, 502213, 502243, 502328, 502329, 4232135, B01J 2106, B01J 2108, B01J 2358, B01J 2360

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active

049771299

ABSTRACT:
A catalyst suitable for use as a three-way catalyst having low H.sub.2 S emissions for emission control and with substantially no ceria present is made with a refractory oxide particle or powder support having deposited thereon about 0.5-20% by weight of a non-rate earth oxide stabilizer, at least 0.5 to about 5% by weight of an alkali metal oxide as a promoter, and a catalytically-effective amount of one or more platinum group metals. The preferred refractory oxide is alumina and the non-rare earth oxide stabilizer can be an oxide such as ZrO.sub.2, MgO, CaO, SnO, CaO, Y.sub.2 O.sub.3, TiO.sub.2, ZnO, B.sub.2 O.sub.3, P.sub.2 O.sub.5, SnO.sub.2, Bi.sub.2 O.sub.3, or SiO.sub.2 with the preferred oxide being zirconia.

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"Ceria Promoted Three-Way Catalysts for Auto Exhaust Emission Control," G. Kim, I&EC Product Research & Development, 1982, 21, 267.

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