Attenuated superactive multimetallic catalytic composite

Details Attenuated superactive multimetallic catalytic composite Attenuated superactive multimetallic catalytic composite

1979-05-04

1980-11-04

Garvin, Patrick

Compositions

Preservative agents

Anti-oxidants or chemical change inhibitants

252443, 252466PT, 252473, B01J 2708, B01J 2710, B01J 2336

Patent

active

042318971

ABSTRACT:
A novel attenuated superactive multimetallic catalytic composite especially useful for converting hydrocarbons comprises a combination of a catalytically effective amount of a pyrolyzed rhenium carbonyl component with a porous carrier material containing a uniform dispersion of catalytically effective amounts of a platinum group component, which is maintained in the elemental metallic state during the incorporation of the rhenium carbonyl component, and of a cadmium component. In a highly preferred embodiment, this novel catalytic composite also contains a catalytically effective amount of a halogen component. The platinum group component, pyrolyzed rhenium carbonyl component, cadmium component and optional halogen component are preferably present in the multimetallic catalytic composite in amounts, calculated on an elemental basis, corresponding to about 0.01 to about 2 wt. % platinum group metal, about 0.01 to about 5 wt. % rhenium, about 0.01 to about 5 wt. % cadmium and about 0.1 to about 3.5 wt. % halogen. A key feature associated with the preparation of the subject catalytic composite is reaction of a rhenium carbonyl complex with a porous carrier material containing a uniform dispersion of a cadmium component and of a platinum group metal maintained in the elemental state, whereby the interaction of the rhenium moiety with the platinum group moiety is maximized due to the platinophilic (i.e. platinum-seeking) propensities of the carbon monoxide ligands associated with the rhenium reagent.

REFERENCES:
patent: 3951782 (1976-04-01), Buss
patent: 3997429 (1976-12-01), Rashkin
patent: 4157989 (1979-06-01), Antos

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