Atomic layer deposition methods

Single-crystal – oriented-crystal – and epitaxy growth processes; – Forming from vapor or gaseous state – With decomposition of a precursor

Reexamination Certificate

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C117S084000, C117S102000, C117S104000, C117S105000, C117S950000, C257S021000

Reexamination Certificate

active

07077902

ABSTRACT:
An aluminum-containing material deposition method includes depositing a first precursor on a substrate in the substantial absence of a second precursor. The first precursor can contain a chelate of Al(NR1R2)x(NR3(CH2)zNR4R5)yor Al(NR1R2)x(NR3(CH2)zOR4)y; where x is 0, 1, or 2; y is 3−x; z is an integer 2 to 8; and R1to R5are independently selected from among hydrocarbyl groups containing 1 to 10 carbon atoms with silicon optionally substituted for one or more carbon atoms. The method includes depositing the second precursor on the first deposited precursor, the second precursor containing a nitrogen source or an oxidant. A deposition product of the first and second precursors includes at least one of an aluminum nitride or an aluminum oxide. The deposition method can be atomic layer deposition where the first and second precursors are chemisorbed or reacted as monolayers. The first precursor can further be non-pyrophoric.

REFERENCES:
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patent: 5908947 (1999-06-01), Vaartstra
patent: 6287965 (2001-09-01), Kang et al.
patent: 6391803 (2002-05-01), Kim et al.
patent: 6730163 (2004-05-01), Vaartstra
patent: 2002027063 (2002-04-01), None
Sean T. Barry, et al, “Monomeric Chelated Amides of Aluminum and Gallium: Volatile, Miscible Liquid Precursors for CVD”, Harvard University Chemical Laboratories, Mater. Res. Soc. Symp. Proc., 2000, vol. 606, p. 83.
Kim et al., “Compositional Variations of TiAlN Films Deposited by Metalorganic Atomic Layer Desposition Method”, Jpn. J. Applied Physics, vii, 41, part I (2a) Feb. 2002, pp. 562-565.

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