Chemistry: analytical and immunological testing – Oxygen containing – Ozone or peroxide
Reexamination Certificate
1999-03-23
2002-09-03
Ludlow, Jan (Department: 1743)
Chemistry: analytical and immunological testing
Oxygen containing
Ozone or peroxide
C073S031020, C116S202000, C116S212000, C356S433000, C422S051000, C422S082050, C422S087000, C436S164000
Reexamination Certificate
active
06444473
ABSTRACT:
BACKGROUND OF THE INVENTION
1. Field of Invention
This invention pertains to measurement of ozone.
2. Description of the Related Art
Ozone is deleterious to materials and to humans. OSHA's limits for average ozone concentration are up to 0.1 ppm over 8 hours or up to 0.3 ppm over 15 minutes.
Presently, there are a number of techniques for measuring atmospheric ozone concentration. One technique employs ultraviolet light absorption whereas another employs the differential creep of rubber technique.
The technique of ultraviolet light absorption takes advantage of a 254 nm absorption line of ozone in the electromagnetic spectra and thus measures the concentration of ozone directly. Here, a measured sample of air is pumped into a chamber and illuminated at one end with a low pressure cold cathode mercury vapor ultraviolet light. The ultraviolet light from the mercury lamp has emission at 254 nm. At the opposite end of the chamber is a cesium telluride vacuum diode detector. The determination of ozone is carried out in two steps. Initially, an ozone-free reference gas sample is pumped into the chamber and the transmitted light intensity is measured. Any ozone present in the reference gas is rapidly destroyed by passing the gas over manganese dioxide. In the second step, an “ozone gas sample” is pumped into the same chamber and the transmitted light is measured. The ozone concentration in the “ozone gas sample” can be easily determined by application of a formula.
Ozone detectors which operate on the basis of ultraviolet light absorption can detect as little as about 0.001 ppm of ozone but have the disadvantage of being somewhat large at about 19″×12″×6.5″; of being heavy at about 22 pounds; of requiring a full line voltage of 115V; of requiring a warmup time of about 2 hours; of being expensive at about $4,500-$12,000 per detector; and of requiring to be stationary. In short, such detectors are sensitive, expensive and are intended for stationary laboratory use.
The fact that a detector must remain in the lab is a serious disadvantage because ozone concentration often needs to be measured in widely separated locations, such as when one is determining the average ozone concentration over an entire city or when one needs to measure the ambient ozone in every room in a building. Furthermore, another critical disadvantage of an absorption ozone detector resides in the fact that ozone is very chemically active and thus easily destroyed inside many containers, which precludes sample collection.
In a differential creep of rubber technique, a standard rubber thread is divided in half, one part is exposed to the atmospheric ozone whereas, the other part is protected from ozone. The unexposed portion creeps at a lower rate than the exposed portion and pulls an indicating needle attached to the exposed rubber along a scale, thus giving a measure of ozone concentration.
SUMMARY OF THE INVENTION
An object of this invention is an apparatus for measuring ozone.
Another object of this invention is a quick measurement of ozone in atmosphere by means of a stretched elastomer which frosts over in response to microcracks created in the elastomer by ozone in the atmosphere.
Another object of this invention is a highly practical and a highly sensitive electrical measurement of light intensity from a frosted elastomer adjusted for light intensity from unfrosted elastomer.
Another object of this invention is a device for providing rudimentary “go-no go” ozone concentration results.
These and other objects of this invention are realized by a structure characterized by a stretched or stressed elastic material which becomes whitened or frosted or transluscent when ozone in the surrounding air contacts it and creates microcracks therein which scatter light.
REFERENCES:
Serrano et al., Atmos. Environ., Part A (1993), 27A(3), pp. 431-442.*
Hong et al., Polym. Degrad. Stab. (1995), 49(3), pp. 437-447.*
Chemical Abstract No. 130:169331, Eng et al., J. Rubber Res. (Kuala Lumpur) (1998), 1(3), pp. 133-145.
Mott Peter H.
Roland Charles M.
Kap George A.
Karasek John J.
Ludlow Jan
The United States of America as represented by the Secretary of
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