Asymmetrical hydrogenation by means of optically active aluminum

Details Asymmetrical hydrogenation by means of optically active aluminum Asymmetrical hydrogenation by means of optically active aluminum

1976-05-10

1977-10-11

Thomas, Jr., James O.

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

2606065P, 260583R, C07C 2914, C07C 2900

Patent

active

040535215

ABSTRACT:
A prochiral or racemic substrate such as a prochiral ketone is converted into an optically active product through a process wherein said substrate is subjected to an asymmetric hydrogen transfer reaction by means of an optically active amino-alane or polyimino-alane represented by the formula

REFERENCES:
patent: 3852262 (1974-12-01), Vit et al.
Giongo et al., Tetrahedron Letter, No. 34, pp. 3195-3198 (1973).

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