Asymmetric synthesis of chiral secondary alcohols

Details Asymmetric synthesis of chiral secondary alcohols Asymmetric synthesis of chiral secondary alcohols

1993-04-26

1994-03-08

Prescott, Arthur C.

Organic compounds -- part of the class 532-570 series

Organic compounds

Carboxylic acid esters

560236, C07C 6902

Patent

active

052929299

ABSTRACT:
A process for producing (R)-2-hydroxy-6-haloalkane is disclosed. In the first step, a cyclic alkanol is photohalogenated. In the second step, the photohalogenation product is reacted with a chiral catalyst and dialkyl zinc to produce (R)-2-hydroxy-6-haloalkane.

REFERENCES:
patent: 4095038 (1978-06-01), Boguth et al.
patent: 4314072 (1982-02-01), Syrier
patent: 5041613 (1991-08-01), McCombs

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