Asymmetric ligands useful for transition metal catalyzed bond fo

Details Asymmetric ligands useful for transition metal catalyzed bond fo Asymmetric ligands useful for transition metal catalyzed bond fo

1995-06-07

1999-07-06

Gerstl, Robert

Organic compounds -- part of the class 532-570 series

Organic compounds

Heterocyclic carbon compounds containing a hetero ring...

548479, C07C 2900

Patent

active

059199482

ABSTRACT:
A novel ligand having the Formula 1 structure has proved remarkably successful in the amination of butadiene monoepoxide, which is a potentially desirable substrate for an asymmetric synthesis providing access to each enantiomer of vinylglycinol. ##STR1## This and other ligands described are useful for chiral induction of bond forming reactions with an epoxide substrate.

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