Asymmetric amination of 1,3-dienes

Details Asymmetric amination of 1,3-dienes Asymmetric amination of 1,3-dienes

1979-03-19

1980-05-27

Doll, John

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

252431P, 260563R, 260563C, 260563P, 260574, 260576, 260577, 260583H, 260584B, 544178, 544403, 544404, 546184, 546192, C07D20706, C07C 8518

Patent

active

042049970

ABSTRACT:
A process for the asymmetric synthesis of amines which comprises the amination of a conjugated diene having from 4 to about 20 carbon atoms in the presence of a catalyst system comprising a palladium compound and an optically active phosphine ligand containing at least two phosphorus atoms.

REFERENCES:
patent: 4008281 (1977-02-01), Knowles et al.
patent: 4120901 (1978-10-01), Hobbs et al.
Dzhemilev et al., "IZV. AKAD. NAUK SSSR, SER. KHIM", No. 10, pp. 2379-2380 (1975).

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