Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal
Patent
1978-03-13
1980-01-08
Reamer, James H.
Chemistry of carbon compounds
Miscellaneous organic carbon compounds
C-metal
2603405R, C07C 4984, C07D31706
Patent
active
041827295
ABSTRACT:
Aryl substituted diketones and keto-esters, useful as antiviral agents and insecticides, are prepared by reacting an arylalkyl or arylalkenyl iodide with a metal salt of the appropriate diketone or keto-ester. The intermediate iodides are prepared by condensing a methyl cyclopropyl ketone with an aromatic aldehyde to give an arylvinyl cyclopropyl ketone, reducing the latter to an arylethyl cyclopropyl carbinol or arylvinyl cyclopropyl carbinol, treating the carbinol with phosphorus tribromide and then with zinc bromide to give an arylalkyl or arylalkenyl bromide, and then replacing the bromine atom by iodine.
REFERENCES:
patent: 3458565 (1969-07-01), Bicking
patent: 3878200 (1975-04-01), Diana et al.
patent: 4005103 (1977-01-01), Teulon
Johnson Thomas L.
Reamer James H.
Sterling Drug Inc.
Wyatt B. Woodrow
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