Arylsulfinate salts in initiator systems for polymeric...

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Compositions to be polymerized by wave energy wherein said...

Reexamination Certificate

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C522S059000, C522S050000, C526S193000, C526S198000

Reexamination Certificate

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07030169

ABSTRACT:
Compositions are provided that that can be used as an initiator system for free radical polymerization reactions. More specifically, the initiator systems include an electron acceptor and an electron donor. The electron donors are arylsulfinate salts having a cation that contains at least one carbon atom and either a positively charged nitrogen atom or a positively charged phosphorus atom. Methods of polymerization are also provided that can be used to prepare polymeric material with the initiator systems. The initiator systems can be thermal initiator systems, photoinitiator systems, or combinations thereof.

REFERENCES:
patent: 3556794 (1971-01-01), Margerum
patent: 3573922 (1971-04-01), Rust
patent: 3607272 (1971-09-01), Rust
patent: 3623875 (1971-11-01), Desjarlais
patent: 3627656 (1971-12-01), Miller et al.
patent: 3642487 (1972-02-01), Rust
patent: 3708296 (1973-01-01), Schlesinger
patent: 3729313 (1973-04-01), Smith
patent: 3741769 (1973-06-01), Smith
patent: 3788858 (1974-01-01), Margerum
patent: 3808006 (1974-04-01), Smith
patent: 4069054 (1978-01-01), Smith
patent: 4069055 (1978-01-01), Crivello
patent: 4182035 (1980-01-01), Yamauchi et al.
patent: 4216288 (1980-08-01), Crivello
patent: 4250053 (1981-02-01), Smith
patent: 4250311 (1981-02-01), Crivello
patent: 4257915 (1981-03-01), Eaton
patent: 4259075 (1981-03-01), Yamauchi et al.
patent: 4356296 (1982-10-01), Griffith et al.
patent: 4366228 (1982-12-01), Specht et al.
patent: 4394403 (1983-07-01), Smith
patent: 4455147 (1984-06-01), Lewis et al.
patent: 4499251 (1985-02-01), Omura et al.
patent: 4503169 (1985-03-01), Randklev
patent: 4537940 (1985-08-01), Omura et al.
patent: 4539382 (1985-09-01), Omura et al.
patent: 4642126 (1987-02-01), Zador et al.
patent: 4650913 (1987-03-01), Feiring
patent: 4652274 (1987-03-01), Boettcher et al.
patent: 4665217 (1987-05-01), Reiners et al.
patent: 4695251 (1987-09-01), Randklev
patent: 4752338 (1988-06-01), Reiners et al.
patent: 4755620 (1988-07-01), Iwamoto et al.
patent: 4859572 (1989-08-01), Farid et al.
patent: 4871786 (1989-10-01), Aasen et al.
patent: 4872936 (1989-10-01), Engelbrecht
patent: 4908227 (1990-03-01), Dougherty et al.
patent: 4959297 (1990-09-01), Palazzotto
patent: 4966934 (1990-10-01), Huang et al.
patent: 4971892 (1990-11-01), Ali et al.
patent: 4983644 (1991-01-01), Mukai et al.
patent: 5076844 (1991-12-01), Fock et al.
patent: 5084586 (1992-01-01), Farooq
patent: 5089374 (1992-02-01), Saeva
patent: 5105006 (1992-04-01), Parker
patent: 5124417 (1992-06-01), Farooq
patent: 5130347 (1992-07-01), Mitra
patent: 5154762 (1992-10-01), Mitra et al.
patent: 5256447 (1993-10-01), Oxman et al.
patent: 5304585 (1994-04-01), Bunker
patent: 5486544 (1996-01-01), Kawashima et al.
patent: 5501727 (1996-03-01), Wang et al.
patent: 5530038 (1996-06-01), Yamamoto et al.
patent: 5545676 (1996-08-01), Palazzotto et al.
patent: 5607663 (1997-03-01), Rozzi et al.
patent: 5662887 (1997-09-01), Rozzi et al.
patent: 5866630 (1999-02-01), Mitra et al.
patent: 5876208 (1999-03-01), Mitra et al.
patent: 5888491 (1999-03-01), Mitra et al.
patent: 5998495 (1999-12-01), Oxman et al.
patent: 6017660 (2000-01-01), Palazzotto et al.
patent: 6030606 (2000-02-01), Holmes
patent: 6187833 (2001-02-01), Oxman et al.
patent: 6204302 (2001-03-01), Rawls et al.
patent: 6312668 (2001-11-01), Mitra et al.
patent: 6331080 (2001-12-01), Cole et al.
patent: 6387981 (2002-05-01), Zhang et al.
patent: 6444725 (2002-09-01), Trom et al.
patent: 6566413 (2003-05-01), Weinmann et al.
patent: 6624236 (2003-09-01), Bissinger et al.
patent: 6759177 (2004-07-01), Shimada et al.
patent: 2003/0054288 (2003-03-01), Shimada et al.
patent: 2003/0166816 (2003-09-01), Bissinger et al.
patent: 2 215 474 (1973-10-01), None
patent: 0 201 031 (1986-11-01), None
patent: 0 201 778 (1986-11-01), None
patent: 0 237 233 (1987-09-01), None
patent: 0 373 384 (1990-06-01), None
patent: 0375160 (1990-06-01), None
patent: 0 661 034 (1995-07-01), None
patent: 0 712 622 (1996-05-01), None
patent: 1 051 961 (2000-11-01), None
patent: 1 269 967 (2003-01-01), None
patent: 9-34110 (1997-02-01), None
patent: 2002-341519 (2002-11-01), None
patent: WO 00/38619 (2000-07-01), None
patent: WO 00/42092 (2000-07-01), None
patent: WO 01/07444 (2001-02-01), None
patent: WO 01/30306 (2001-05-01), None
patent: WO 01/30307 (2001-05-01), None
patent: WO 01/92271 (2001-12-01), None
patent: WO 02/092021 (2002-11-01), None
Connors, K. A., “Chemical Kinetics, The Study of Reaction Rates in Solution”, VCH, 1990, Chapter 2.
Rodrigues et al., “Cationic Photopolymerization Of Tetrahydrofuran: A Mechanistic Study On The Use Of A Sulfonium Salt-Phenothiazine Initiation System”, Journal of Polymer Science: Part A: Polymer Chemistry, vol. 39, pp. 46-55, 2001.
Gomurashvili et al., “Phenothiazine Photosensitizers For Onium Salt Photoinitiated Cationic Polymerization”, Journal of Polymer Science: Part A: Polymer Chemistry, vol. 39, pp. 1187-1197, 2001.
Crivello et al., “Dye-Sensitized Photoinitiated Cationic Polymerization. The System: Perylene-Triarylsulfonium Salts”, General Electric Corporate Research and Development, Schenectady, NY, pp. 1059-1065.
“Pigments-Inorganic” and “Pigments-Organic”, Kirk-Othmer Encyclopedia of Chemical Technology, Third ed., vol. 17, pp. 788-871, John Wiley & Sons, NY, 1982.
Pearson, “Photoconductive Polymers”, Pure and Appl. Chem., 49, pp. 463-477, 1977.
Beringer et al., “Diaryliodonium Salts. IX. The Synthesis of Substituted Diphenyliodonium Salts”, Am. Chem. Soc., 81, 342-351 (1959).
Dorman et al., “Carbon-13 Nuclear Magnetic Resonance Spectroscopy. Quantitative Correlations of the Carbon Chemical Shifts of Acyclic Alkenes”, J. Org. Chem., 36, 2757-2766 (1971).
Sims et al., “Studies on the Mechanism by Which Cyanine Dyes Measure Membrane Potential in Red Blood Cells and Phosphatidylcholine Vesicles”, Biochemistry, vol. 13, No. 16, 3315-3330 (1974).
Safran et al., “Phase Diagrams for Microemulsions”, Phys.Rev.Lett., vol. 50, No. 24, pp. 1930-1933 (1983).
Buonocore et al., “A Report on A Resin Composition Capable Of Bonding To Human Dentin Surfaces”, J.Dent.Res., vol. 35, No. 6, pp. 846-851 (1956).
Leung et al., “Microemulsions: Formation, Structure, Properties, and Novel Applications”, Surfactants in Chemical/Process Engineering, Marcel Dekker, Inc. NY, vol. 28, Chapter 9, pp. 315-367 (1988).
Ostrovsky et al., “Mechanism of Microemulsion Formation In Systems With Low Interfacial Tension: Occurrence, Properties, and Behavior of Microemulsions”, J.Colloid.Interface.Sci., vol. 102, No. 1, pp. 206-226 (1984).

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