Arylation of olefins

Organic compounds -- part of the class 532-570 series – Organic compounds – Nitriles

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548197, 548202, 546180, 546346, 560 9, 560 20, 560 47, 560 55, 560 81, 560105, 562426, 562438, 562456, 562465, 562496, 564442, 568316, 568433, 568649, 568655, 570191, 570194, C07C12166, C07C 69612

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046042431

ABSTRACT:
An olefin, especially an activated olefin, is arylated by reaction with an arylamine, such as an aniline, in an inert polar organic solvent and in the presence of an alkyl nitrite, a hydrogen halide, and a catalytic amount of a copper catalyst having the copper in an oxidation state below +2.

REFERENCES:
Doyle et al., J. Org. Chem., vol. 42, pp. 2431-2436, (1977).
Kawamatsu et al., Arzneim.-Forsch./Drug Res., vol. 30(I), No. 5, pp. 751-758, (1980).
Rondestvedt, Jr., Organic Reactions, vol. 11, pp. 189-260.
Rondestvedt, Jr., Organic Reactions, vol. 24, pp. 225-259.

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