Aryl ketals of polycyclic oxo compounds and processes

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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C07D31744

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039608964

ABSTRACT:
The intermediates and processes of this disclosure provide a new stereo-specific total synthesis of steroidal materials having known valuable pharmacological properties. A fundamental feature of this diclosure is the utilization of aryl ketals, preferably phenylenedioxy ketals derived from catechol as protective groups for oxo moieties in the polycyclic intermediates used in the aforesaid total synthesis.

REFERENCES:
patent: 3655695 (1972-04-01), Andrews et al.
Blickenstaff et al., Organic Chemistry-A Series of Monographs vol. 30-Total Synthesis of Steroids, pp. 20- 22 and 269.
Fried et al., Organic Reactions in Steroid Chemistry, Van Nostrand Reinhold Co., 1972, vol. 1 pp. 121-122.

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