Aryl carboxylate process

Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing

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560108, 560109, 560130, 560130, 568768, 568781, C07C 3910, C07C 6976

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active

046956581

ABSTRACT:
A process for replacing an aromatic carbon-thallium bond with a carbon-oxygen bond. The process is particularly suitable for producing specific aromatic isomers by thallating an aromatic compound and replacing the thallium with a carboxylate group which can be further hydrolyzed if desired to form an aromatic hydroxyl compound.

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McKellop, A., and Taylor, E. C., Chemistry in Britain, "Thallium in Organic Synthesis", vol. 9, No. 4 (1973) pp. 4 to 11.
Taylor, E. C. et al., "Thallium in Organic Synthesis XV, Synthesis of Phenols and Aromatic Nitriles," J.A.C.S., 92, pp. 3520-3522 (1970).
Taylor, E. C. et al., "Thallium in Organic Synthesis XXIII, Elec. Aromatic Thallation", J.A.C.S., 93:19 (Sep. 22, 1971) pp. 4845-4850.

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