Articles incorporating pressure-sensitive adhesives having impro

Stock material or miscellaneous articles – Web or sheet containing structurally defined element or... – Adhesive outermost layer

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428344, 428355R, 428355EN, 428355CN, 428355AC, 428461, 428463, 428518, 428522, 428141, 1562733, 1562755, 1562757, 156327, 1563309, B32B 2706, B32B 3104

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058612114

ABSTRACT:
Articles comprising a substrate, preferably a retroreflective sheeting, having a coating of a pressure-sensitive adhesive composition, and articles wherein the adhesive adheres the substrate to a highly monomericly plasticized PVC component, preferably a PVC coated fabric. The adhesive comprises a crosslinked copolymer of a first monofunctional acrylate ester of a non-tertiary alcohol having as a homopolymer a glass transition temperature of less than -25.degree. C., a nitrogen containing moderately basic monomer copolymerizable therewith selected from the group consisting of N,N-dialkyl substituted amides, an optional copolymerizable acidic monomer, an optional second monofunctional acrylate ester of a non-tertiary alcohol having as a homopolymer a glass transition temperature -25.degree. C. or greater, and a crosslinking agent. A method of bonding a highly monomericly plasticized PVC component to a substrate, preferably a retroreflective sheeting, using the adhesive.

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