Article and method for determining the concentration of metal io

Chemistry: electrical and wave energy – Processes and products

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204418, G01N 2730, G01N 2758

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active

046345019

ABSTRACT:
A device and method for determining the concentration of dicyanoaurate anions in a solution is disclosed. The device includes a semipermeable membrane formed from a material permeable to dicyanoaurate anions. The material may be comprised of an organopolysiloxane-polycarbonate block copolymer and a complexed salt of the dicyanoaurate anion.

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Zarinskii et al., Second Symposium on Ion-Selective Electrodes, 1976, E. Pungor and I. Buzas, editors, (pub. 1977), pp. 245-253 [Chem. Abst. 88,98595n (1978)], "New Liquid State Membrane Electrodes for Rhenium(VII) and Gold(I,III) Based on Ion-Associated Systems".
Avdeeva et al., Anal. Khim. 37, 1434-1440 (1982) (Russ) [Chem. Abst. 98, 45987s], "Plasticized Ion-Selective Electrodes for Determination of Gold in Chloride and Cyanide Solutions", J. Anal. Chem. USSR 37, 1102-1107 (1983).
Bychkov et al., Liquid Ion-Selective Electrode for Determining Gold in Cyanide Solutions, Zh. Anal. Khim. 1976, 31(11), 2114-2119 (Russ.), Chem. Abstracts 86, 1823439f (1977).
Gordievskii et al., Composition of Ion-Selective Electrode Membrane for Determination of Dicyanoaurate Ions, USSR SU 957,086, Dec. 3, 1980; Chem. Abs. 98, 136829h (1983).
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Golubev et al., Effect of Extraction Characteristics of the System Electrolyte-Liquid Membrane on the Electrode Function of a Dicyanoaurate (I) Electrode, Latv. PSR Zinat. Akad. Vestis Kim. Ser. 1983, (1), 45-7 (Russ.); Chem. Abs. 98, 151672v (1983).

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