Artemisinins with improved stability and bioavailability for...

Drug – bio-affecting and body treating compositions – Designated organic active ingredient containing – Carbohydrate doai

Reexamination Certificate

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C514S060000, C514S557000, C514S772200, C514S772300, C514S773000, C514S777000, C514S779000, C514S781000, C514S054000, C514S895000, C514S023000, C426S096000, C424S440000, C424S493000, C424S500000, C549S348000, C536S103000, C536S120000, C536S122000, C536S123100

Reexamination Certificate

active

06951846

ABSTRACT:
A stable form of artemisinin wherein an artelinic acid or artesunic acid is complexed with cyclodextrin analogs, preferably, β-cyclodextrin. The complexed cyclodextrin artemisinin formulation shields the peroxide portion of the artemisinin backbone from hydrolytic decomposition rendering it stable in solution. Artelinic acid and cyclodextrin are placed into contact with one another to yield a 2:1 molecular species. Artesunic acid and cyclodextrin yield a 1:1 molecular species. The complexed cyclodextrin artemisinin formulation is effective for the treatment of malaria and is stable in solution for long periods of time.

REFERENCES:
patent: 6586464 (2003-07-01), Posner et al.
patent: 2002/0147177 (2002-10-01), Yuen et al.
patent: 685391 (1995-06-01), None
patent: WO/85 02767 (1983-12-01), None
patent: WO 01/62299 (2000-02-01), None
Usuda et al. “Interaction of Antimatarial agent artemisinin with cyclodextrins.” Drug Development and Industrial Pharmacy, 26(6 613-19, 2000.
Bayomi, M. “Characterization of Arteether Interactions with Beta-cyclodextrin and hydroxypropyl-beta-cyclodextrin”, Saudi Pharmaceutical Journal, Saudi Pharm. Soc., vol. 10, No. 1/2, Jan. 2002, pp 36-43.
Usuda M., et al., “Interaction of antimalarial agent artemisinin with cyclodextrins”, Drug Dev. and Industrial Pharmacy, New York, NY, US, vol. 26, No. 6, Jun. 2000, pp. 613-619.
Wong, J. et al., “Improved oral bioavailability of artemisinin through inclusion complexation with bets-and gamma-cyclodextrins”, Internat. Jour. of Pharmaceutics, Amsterdam, NL, vol. 227, No. 1-2, 2001, pp. 177-185.
Szejtli, Cyclodextrin Technology, textbook, (1988) Kluwer Academic Publishers, p. 186-193, ISBN#90-227-2314-1.
Iiiapakurthy, et al. Abstract Interactionof artemisinin and its related compounds with hydroxypropyl-beta-cyclodextrin in solution state: Experimental and molecular-modeling studies. (2003).

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