Specialized metallurgical processes – compositions for use therei – Processes – Producing or treating free metal
Reexamination Certificate
1998-12-04
2001-04-24
Andrews, Melvyn (Department: 1742)
Specialized metallurgical processes, compositions for use therei
Processes
Producing or treating free metal
C075S489000
Reexamination Certificate
active
06221126
ABSTRACT:
BACKGROUND OF THE INVENTION
The invention relates to an arrangement for the reduction of metal-oxide-bearing material, particularly of iron ore, with a reduction vessel, for example, a shaft furnace, in which the metal-oxide-bearing material is reduced in counterflow with reduction gas and which is provided with an inlet for metal-oxide-bearing material, an inlet for reduction gas, an outlet for off-gas and an outlet for reduced material, a vessel for metal-oxide-bearing material which is connected with the reduction vessel by means of a line, and a first supply line for sealing gas which serves to seal the reduction vessel against the vessel, which first supply line is provided at the connecting line between the vessel and the reduction vessel.
Arrangements of this type are known (Direct from Midrex, Vol. 14, No. 4, 3rd quarter of 1989).
According to DE-A - 34 32 090, sulfur-bearing ore is reduced in a shaft furnace in counterflow with reduction gas. The off-gas exiting the furnace is divided into two flows, the first flow being used for preheating and desulfurization of the ore which is located in an ore bin above the shaft furnace and then fed to an overall converter for heating purposes and the second flow being fed together with hydrocarbons to a catalytic gas converter for the purpose of generating reduction gas.
Above the ore bin of the arrangement described in DE-A - 34 32 090, a container is located from which ore is charged into the ore bin. Inert gas is injected into the connection between this container and the ore bin in order to prevent sulfur-bearing off-gas from exiting the ore bin through this connection. This measure thus serves to establish a gas seal.
A shaft furnace for the reduction of metal-oxide-bearing material which is charged from an ore bin into the shaft furnace by means of downpipes is also known from U.S. Pat. No. 4,178,151.
U.S. Pat. No. 4,212,452 describes a plant in which iron oxide is reduced to sponge iron in a shaft furnace through the addition of solid carbon-bearing material which is gasified in an upper zone of the shaft furnace and through the addition of reduction gas containing CO and H
2
in a central zone of the shaft furnace. The iron oxide, together with the solid carbon-bearing material, is charged from the top into the shaft furnace and flows through the shaft furnace from the top to the bottom partly cocurrently and partly countercurrently to the reduction gases. In a lower zone of the shaft furnace, the sponge iron formed by reduction is cooled with cool, dry reduction gas. The shaft furnace is sealed towards the top and bottom with one CO
2
-operated gas seal each in order to prevent the undesirable excape of reduction gas from the shaft furnace, CO
2
being recovered therein from waste reduction gas through gas scrubbing. This known arrangement has the disadvantage that the sealing gas, CO
2
, may enter the shaft furnace, which is undesirable with regard to reduction.
An arrangement which is used, for example, for the direct reduction of iron-oxide-bearing material by means of reduction gas in a shaft furnace is known from U.S. Pat. No. 3,850,616. The iron-oxide-bearing material flows through the shaft furnace from the top to the bottom countercurrently to the reduction gas and is cooled with cool reduction gas in the lower zone of the shaft furnace. In order to prevent reduction gas from exiting the shaft furnace, a gas seal operated with inert gas is provided at the lower end of the shaft furnace. This known arrangement has the disadvantage of high consumption of expensive inert gas.
Processes in which iron-oxide-bearing material is reduced in a shaft furnace by means of reduction gas and melted in a melting unit which is structurally connected with the shaft furnace are known from U.S. Pat. Nos. 4,248,626 and 4,270,740. In the melting unit, reduction gas is generated by coal gasification. The reduction gas is withdrawn from the melting unit and cooled before it is charged into the shaft furnace in order to prevent the material reduced in the shaft furnace from agglomerating.
In order to prevent the very hot reduction gas from being carried over from the melting unit directly into the shaft furnace, a gas seal is provided in the direct connection between the melting unit and the shaft furnace.
The applicant further knows that gas seals operated with nitrogen, which seal shaft furnaces against the environment, are customary. Gas seals of this type have the disadvantage that the generation of nitrogen involves high technical expenditure, which results in high costs because large amounts of nitrogen are consumed.
The technical problem of the present invention is to eliminate this disadvantage and to provide an arrangement of the type described above which can be operated with a less expensive sealing gas.
SUMMARY OF THE INVENTION
The invention is characterized in that at an arrangement for the reduction of metal-oxide-bearing material, particularly of iron ore, with a reduction vessel in which the metal-oxide-bearing material is reduced in counterflow with reduction gas and which is provided with an inlet for metal-oxide-bearing material, an inlet for reduction gas, an outlet for off-gas and an outlet for reduced material, a vessel for metal-oxide-bearing material which is connected with the reduction vessel by means of a line and a first supply line for a sealing gas which serves to seal the reduction vessel against the vessel, which first supply line is provided at the connecting line between the vessel and the reduction vessel, at least one additional supply line for a sealing gas is provided at the connecting line, which additional supply line is located between the first supply line and the vessel.
Thus, at least one additional gas seal is provided in the arrangement according to the invention, which does not have to be inert to the reactions occurring in the reduction vessel and thus can be a less expensive gas. This gas assumes the function of the main sealing gas. The other gas seal, which is operated with a gas that is inert to the reactions occurring in the reduction vessel, for example, nitrogen or carbon dioxide, assumes the function of an auxiliary gas seal and moreover prevents the main sealing gas from entering the reduction vessel. In this way, considerably less inert gas is consumed than required according to prior art.
In the arrangement according to the invention, the line connecting the vessel with the reduction vessel preferably comprises a sealing leg and downpipes, the supply lines for sealing gas being provided at the sealing leg.
Off-gas from the reduction vessel can be used for operating the main gas seal. In this case, the outlet for off-gas is connected with the sealing leg by means of a line and a burner for the combustion of off-gas and a cooling device, for example, a heat exchanger or a scrubber, for cooling the off-gas combusted in the burner are provided in the arrangement according to the invention. Furthermore, a compressor is expediently provided, which is connected downstream of the cooling device.
Another preferred embodiment of the arrangement according to the invention is characterized in that an additional sealing leg is provided at the reduction vessel, which is located at the lower end of the reduction vessel, and in that at least two additional supply lines for sealing gas are provided at the sealing leg, one of which is connected with the first supply line for off-gas. In this case, it is expedient to provide a cooling device in the supply line.
The invention further relates to a process for the reduction of metal-oxide-bearing material, particularly of iron ore, with reduction gas in a reduction vessel, the metal-oxide-bearing material being charged from a vessel into the reduction vessel and conveyed through the latter in counterflow with the reduction gas, wherein the reduction vessel is sealed against the vessel by means of a first gas seal, which is operated with a first gas which is inert to the reduction of the metal-oxide-bearing material, which process is characterized i
Andrews Melvyn
Ostrolenk Faber Gerb & Soffen, LLP
Voest-Alpine Industriean-lagenbau GmbH
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