Aromatic sulfonic acid ester derivative, polyarylene,...

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Mixing of two or more solid polymers; mixing of solid...

Reexamination Certificate

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Details

C525S332400, C525S288000, C525S291000, C528S086000, C528S171000, C528S255000, C528S219000, C528S373000

Reexamination Certificate

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10642694

ABSTRACT:
Disclosed is an aromatic sulfonic acid ester derivative represented by the formula (1);in the formula, X is an atom or a group selected from a halogen atom excluding fluorine, —OSO3CH3and —OSO3CF3, A is a divalent electron attractive group, B is a divalent electron donating group or a direct bonding, Rais a hydrocarbon group of 1 to 20 carbon atoms, Ar is an aromatic group having a substituent of —SO3Rb(wherein Rbis a hydrocarbon group of 1 to 20 carbon atoms), m is an integer of 0 to 10, n is an integer of 0 to 10 and k is an integer of 1 to 4. Also disclosed is a process for producing a polyarylene having a sulfonic acid group, which process comprises the steps of coupling polymerization of an aromatic compound containing the derivative of the formula (1), to prepare a polyarylene and hydrolysis of the polyarylene, and which process has high safety and is easily capable of controlling the amount of sulfonoc acid group introduced into a polymer and the introducing position thereof.

REFERENCES:
patent: 2002/0164513 (2002-11-01), Asano et al.
patent: 102 01 886 (2002-08-01), None
patent: 0 041 780 (1981-12-01), None
patent: 1 138 712 (2001-10-01), None
patent: 1 245 554 (2002-10-01), None

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