Aromatic sulfonation reactions

Organic compounds -- part of the class 532-570 series – Organic compounds – Amino nitrogen containing

Reexamination Certificate

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Reexamination Certificate

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07009077

ABSTRACT:
A process for the sulfonation of an aromatic compound wherein the aromatic compound and sulfonating agent are admixed in the presence of an ionic liquid is described. The method for the sulfonation of aromatic compounds in (e.g. water stable) ionic liquids offers advantages over conventional sulfonation reactions. These are that no by-products form, the ionic liquid is not consumed, and the sulfonating agent (e.g. SO3) is relatively inexpensive.

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W. V. Farrar, “Reactions of some arenesulphonyl chlorides,”J. Chem. Soc., No. 7, Jul. 1960, pp. 3063-3069.
C. J. Adams et al., “Friedel-Crafts reactions in room temperature ionic liquids,”Chem. Commun., No. 19, Oct. 1998, pp. 2097-2098.

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