Aromatic polymers

Chemistry of carbon compounds – Miscellaneous organic carbon compounds

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260 47R, 260590D, 260607A, C08G 6540, C08G 7520

Patent

active

040511090

ABSTRACT:
Aromatic polymers containing benzenoid groups and oxygen atoms in the polymer chains are made by the action of an alkali metal hydroxide on a dihalogeno-benzenoid compound in which each halogen atom is activated by an inert electron-attracting group such as --SO.sub.2 --. When a bis-(4-halogenophenyl) sulphone is reacted with an alkali metal hydroxide, the alkali metal salt of a 4-(4-halogenophenylsulphonyl)phenol is formed as a readily isolated intermediate which polymerizes in the presence or absence of solvent to give a polymer having repeating units of the structure ##STR1##

REFERENCES:
patent: 3634355 (1972-01-01), Barr et al.
Szmant et al., JACS, vol. 78 (1956) pp. 4384-4385.

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