Chemistry of carbon compounds – Miscellaneous organic carbon compounds
Patent
1974-12-19
1977-03-08
Anderson, Harold D.
Chemistry of carbon compounds
Miscellaneous organic carbon compounds
260 306R, 260 308R, 260 326NA, C08G 6932
Patent
active
040112039
ABSTRACT:
A process for producing novel aromatic polyamides having excellent heat resistance, toughness and chemical resistance and further having improved solubility, molding properties and light resistance, which comprises polycondensing a mixed diamine consisting of piperazine and p-phenylenediamine with a substantially equimolar amount of terephthaloyl dihalide in at least one amide type polar solvent (e.g. hexamethylphosphoramide, N-methyl-2-pyrrolidone, alone or a mixture thereof), wherein said piperazine is contained in a ratio of 10 to 35 % by mol on the basis of the whole mixed diamine component, and fibers produced from the aromatic polyamides having high tenacity, flexing characteristics and wear resistance and further having improved elongation ratio, knot tensile strength, fatigue resistance and fibrillation resistance.
REFERENCES:
patent: 2913433 (1959-11-01), Wittbecker et al.
Katsuo Kenichi
Konomi Tuyoshi
Yamaguchi Masayasu
Yukimatsu Keiji
Anderson Harold D.
Toyobo Co. Ltd.
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