Aromatic carboxylic acids, acid halides thereof and...

Organic compounds -- part of the class 532-570 series – Organic compounds – Carboxylic acids and salts thereof

Reexamination Certificate

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C562S488000, C562S840000

Reexamination Certificate

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06949674

ABSTRACT:
A novel aromatic carboxylic acid useful as a material for macromolecular compounds and, in particular, for polycondensed macromolecular compounds exhibiting excellent heat resistance, an acid halide derivative thereof and a process for producing these compounds are disclosed. The aromatic carboxylic acid and the acid halide derivative thereof have structures represented general formulae (1) and (2), respectively, and can be efficiently produced from a dialkyl ester derivative of isophthalic acid and an acetylene derivative in accordance with the disclosed process comprising specific steps.In the above formulae, A represents:in-line-formulae description="In-line Formulae" end="lead"?—C≡C—R1  (a)in-line-formulae description="In-line Formulae" end="tail"?or(R1represents hydrogen atom, an alkyl group or an aromatic group, R2represents an alkyl group or an aromatic group) and X represents a halogen atom.

REFERENCES:
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patent: 6518390 (2003-02-01), Okanuma et al.
patent: 2002/0013443 (2002-01-01), Okanuma et al.
patent: 1 327 653 (2003-07-01), None
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International Search Report, dated Mar. 12, 2002, issued by the Japanese Patent Office, for International Patent No. PCT/JP01/10287 (2 pages).
International Search Report, dated Mar. 12, 2002, issued by the Japanese Patent Office, for International Patent No. PCT/US01/10287 (2 pages).
Crisp, Geoffrey T. et al., “Palladium-Catalysed Coupling of Terminal Alkynes with Aryl Halides Aided by Catalytic Zinc,” Journal of Organometallic Chemistry, 1998, pp. 219-224, vol. 570, No. 2, Elsevier Science S.A. (6 pages).

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