Aromatic alkylation catalyst and method

Catalyst – solid sorbent – or support therefor: product or process – Zeolite or clay – including gallium analogs

Reexamination Certificate

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C502S074000, C502S077000, C502S078000

Reexamination Certificate

active

07060644

ABSTRACT:
A catalyst for use in aromatic alkylation, such as toluene alkylation with methanol, is comprised of a zeolite with pore size from about 5.0 to about 7.0 Å containing a hydrogenating metal. The catalyst may be used in preparing an alkyl aromatic product by providing the catalyst within a reactor. The catalyst may be contacted with an aromatic hydrocarbon and an alkylating agent in the presence of hydrogen under reaction conditions suitable for aromatic alkylation. The catalyst may also be treated to further increase its stability. This is accomplished by heating the hydrogenating metal loaded zeolite catalyst in the presence of a reducing agent prior to use in an aromatic alkylation reaction to a temperature of from about 400° C. to about 500 ° C. for about 0.5 to about 10 hours.

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