Aromatic alkali metal alkene addition process

Chemistry of hydrocarbon compounds – Aromatic compound synthesis – By condensation of entire molecules or entire hydrocarbyl...

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585466, 585467, 585511, 585516, C07C 266, C07C 268, C07C 234

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057057257

ABSTRACT:
A process is provided comprising: (a) contacting a hydrocarbyl lithium with an alkali metal hydrocarbyloxide in the presence of an aromatic compound; and thereafter (b) recovering an aromatic alkali metal compound; and thereafter (c) contacting said aromatic alkali metal compound with an alpha-olefin. Optionally, a catalytic support is also present during steps a, b, and c.

REFERENCES:
patent: 2721885 (1955-10-01), Pines et al.
patent: 3223742 (1965-12-01), Eberhardt
patent: 3607851 (1971-09-01), Forman
patent: 5196622 (1993-03-01), Pettijohn et al.
Eric K. Rideal, Concepts in Catalysis, Academic Press 1968 p. 5.
J. Polymer Science Part A-1 7: pp. 461-469 (1969) no month available.
Tetrahedron Letters No. 2 pp. 257-262 (1966) no month available.

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