Aqueous waste vitrification process and apparatus

Glass manufacturing – Processes – Repairing or cleaning of apparatus; or batch dust prevention...

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65 19, 65 45, 65 62, 65168, 65134, 65181, C03B 502

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active

046664904

ABSTRACT:
A process is provided for treating an aqueous stream of nonradioactive hazardous waste containing inorganic compounds capable of forming oxides upon thermal treatment in which at least one of the oxides is a glass former, glass intermediate or a glass modifier. The process comprises (a) introducing the waste stream into a thermal treatment zone; (b) heating the inorganic compounds in the thermal treatment zone to convert the compounds to the corresponding inorganic oxides and form a melt solution while vaporizing volatile components to form an off-gas; (c) scrubbing the off-gas to provide a ventable flue gas and a liquid condensate with the condensate being recycled to the thermal treatment zone; and (d) removing the melt solution from said thermal treatment zone and cooling the melt solution to form a nonleachable glass containing the hazardous waste. An apparatus particularly adapted to practice the process is also provided.

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