Aqueous vinyl resin emulsion

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – At least one aryl ring which is part of a fused or bridged...

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524808, 524809, 524812, 524813, 524814, 524815, 524816, 524819, 524820, 524821, 524822, 524823, 524824, 524832, 524833, C08L 4300

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active

050176463

ABSTRACT:
(A) 1 to 50% by weight of at least one end carboxyl bearing reactive vinyl monomer of the formula: ##STR1## in which R.sub.1 is hydrogen or methyl group; R.sub.2 is a substituted or unsubstituted aliphatic hydrocarbon having 2 to 10 carbon atoms, alicyclic hydrocarbon having 6 to 7 carbon atoms or aromatic hydrocarbon having 6 carbon atoms; A is a repeating unit of ##STR2## R.sub.3 is ethylene or propylene; R.sub.4 is a substituted or unsubstituted alkylene having 2 to 7 carbon atoms; R.sub.5 is a substituted or unsubstituted alkylene having 2 to 5 carbon atoms; m is an integer of 1 to 10; n is an integer of 2 to 50; X is an inorganic or organic base, and when .alpha., .beta.-ethylenically unsaturated compound(s) (B) hereinunder referred to includes a basic relative monomer, it may be hydrogen atom, and
(B) 99 to 50% by weight of at least one other .alpha., .beta.-ethylenically unsaturated compounds, in an aqueous medium through an emulsion polymerization and removing the said medium therefrom.
The invention also concerns an aqueous emulsion containing said microparticles in a considerable quantity, which is specifically useful in an aqueous paint.

REFERENCES:
Homola, A. and James, R. O., "Preparation and Characterization of Amphoteric Polystyrene Latices," Journal of Colloid and Interface Science, vol. 59, No. 1, 123-134 (1977).
Ishikura et al, U.S. Pat. No. 4,468,493, issued Aug. 28, 1984, "High Solid Coating Composition Containing Novel Microparticles of Crosslinked Copolymer Containing Amphoionic Groups."

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