Organic compounds -- part of the class 532-570 series – Organic compounds – Silicon containing
Patent
1981-08-31
1983-06-28
Shaver, Paul F.
Organic compounds -- part of the class 532-570 series
Organic compounds
Silicon containing
260239B, 260239A, 544 53, 544 56, 544170, 544 3, 544106, 548146, 548206, 548300, 548335, 548347, 548406, 546 14, C07F 710
Patent
active
043907121
ABSTRACT:
There are prepared aqueous solutions of cationic organosilicon compounds which are produced by reacting an alkoxysilylalkyl halide of the formula (RO).sub.3-n R.sub.n.sup.1 --Si--R.sup.2 --X (I) where R is C.sub.1 to C.sub.5 alkyl, methoxy, ethoxy, phenyl, or C.sub.5 to C.sub.8 cycloalkyl; R.sup.1 is C.sub.1 to C.sub.5 alkyl, phenyl, tolyl, benzyl, or C.sub.5 to C.sub.8 cycloalkyl; R.sup.2 is a divalent ethylenic double bond free hydrocarbon group having 3 to 8 carbon atoms, n is zero, 1 or 2 and X is chlorine, bromine, or iodine with a tertiary amine of the formula R.sup.3 NR.sup.4 R.sup.5 (II) where R.sup.3, R.sup.4, and R.sup.5 are the same or different and each is an alkyl group or benzyl in which the number of carbon atoms of the alkyl group or the alkyl groups together is up to 30 or R.sup.4 and .sup.5 together with the nitrogen atom, as well as in a given case a further hetero atom selected from the group consisting of oxygen, nitrogen, and sulfur is a univalent five to eight membered heterocyclic ring having three to seven --CH.sub.2 -- groups in the heterocyclic ring, or R.sup.5 is a C.sub.3 to C.sub.12 cycloalkyl group in aqueous medium at a temperature from room temperature (e.g. about 20.degree. C.) to 300.degree. C. at a mole ratio of (I) to (II) between 1:0.8 to 1:1,2 and in a given case under pressure.
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Buder Wolfgang
Karl Alfons
Kleinschmit Peter
Degussa - AG
Shaver Paul F.
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