Aqueous-dispersed polymer compositions containing cyanoalkyl est

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – At least one aryl ring which is part of a fused or bridged...

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524812, 526312, C08J 3300

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active

052449688

ABSTRACT:
Aqueous-dispersed polymer compositions are prepared comprising polymerized therein (a) monovinylidene aromatic monomer (e.g., styrene), (b) acyclic conjugated diene monomer (e.g., butadiene), and (c) ethylenically unsaturated carboxylic acid monomer(s) (e.g. acrylic and or fumaric acid) and are further benefited by polymerizing therein (d) a cyanoalkyl ester of an ethylenically unsaturated carboxylic acid. The aqueous-dispersed polymers can also comprise polymerized therein an ethylenically unsaturated nitrile monomer such as acrylonitrile. The use of the cyanoalkyl ester, such as 2-cyanoethylmethacrylate (2-CEMA), results in latex polymers with improved performance in paper coating formulations. In particular, paper coatings can be prepared which have improved performance (i.e., wet and dry pick resistance) in offset printing applications.

REFERENCES:
patent: 3575913 (1971-04-01), Meier
patent: 3957710 (1976-05-01), Rohmann et al.
patent: 4364876 (1982-12-01), Kimura et al.

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