Aqueous black enamel composition for glass substrate

Compositions: coating or plastic – Coating or plastic compositions – Alkali metal silicate containing

Reexamination Certificate

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C106S635000, C106S425000, C106S431000, C106S286200, C428S428000, C428S432000

Reexamination Certificate

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07056380

ABSTRACT:
A water-based black enamel composition capable of being deposited on a glass substrate, especially on a glass sheet. The enamel composition includes: 20 to 40% by weight of water-soluble sodium silicate and/or potassium silicate; a water-soluble base, in an amount sufficient for the pH of the composition to be at least 10.5; 5 to 25% by weight of water; 40 to 60% by weight of a metal oxide chosen from the group consisting of copper oxides, iron oxides, cobalt oxides, mixtures of these oxides, and mixtures of at least one of the oxides with chromium oxide(s); less than 10% by weight of zinc oxide; at least 10% by weight of a glass frit having a melting point below 680° C.; and less than 10% by weight of a glass frit having a Littleton point above 700° C. A glazing, especially an automobile glazing, including at least one glass sheet can have at least one of the faces of the glass sheet coated at least partially with the enamel composition.

REFERENCES:
patent: 3883339 (1975-05-01), Michalik et al.
patent: 4486213 (1984-12-01), Lentz et al.
patent: 5518535 (1996-05-01), Boaz
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patent: 5925160 (1999-07-01), Sakoske
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patent: 6261693 (2001-07-01), Veerasamy
patent: 0 658 522 (1995-06-01), None
patent: 1 019 192 (1953-01-01), None
patent: 2 179 526 (1973-11-01), None
patent: 773 031 (1980-10-01), None
patent: WO 96/21629 (1996-07-01), None
Dictionary of Glass-Making—Dictionnaire De Verrerie Glas-Fachwoerterbuch, c/o Instuitut National De Verre, Charleroi, Belgium, p. 136, Ref. No. 3507, 1965.

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