Apparatus for the determination of chemical compounds by chemilu

Chemical apparatus and process disinfecting – deodorizing – preser – Analyzer – structured indicator – or manipulative laboratory... – Chemiluminescent

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23230M, 422 70, 422 89, G01N 2124, G01N 3300

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active

041939638

ABSTRACT:
The invention relates to a process and detector for determining organic and inorganic chemical substances by chemiluminescence with ozone, the selectivity and specificness of the detector being a function of the degree of reactivity of the chemical substances with ozone in distinct temperature ranges. The chemiluminescence reaction takes place in the reaction chamber of the detector, in the absence of oxygen, and with thermal control. The detector comprises the following units: ozone generator, reaction chamber, discharge means for gases issuing from the reaction chamber, an optical system, a photomultiplier, amplifier data transformer and recorder.

REFERENCES:
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patent: 3659100 (1972-04-01), Anderson et al.
patent: 3710107 (1973-01-01), Warren et al.
patent: 3713773 (1973-01-01), Fontijn et al.
patent: 3730686 (1973-01-01), Breitenbach et al.
patent: 3746514 (1973-07-01), Colvin et al.
Fontijn et al., Eviron. Sci. & Tech., pp. 1157-1163, vol. 9., No. 13, Dec. 1975 Homo. Gas Phase Chemiluminescence Meas. of Reactive Hydrocarbons Air Pollutants by Reaction with Oxygen Atoms.
Kummer et al., Chemiluminescent Reactions of Ozone with Olefins & Sulfides., Envir. Science & Tech., vol. 15, No. 10, 10/71.
Pitts; Chem. Reactions of Ozone with Olefins & Organic Sulfides, Advances in Chem. Series 113, ACS., pp. 246-254 (1972).
Ozone Induced Chem. of Organic Compounds Science, vol. 154, (1966).
Kinetics of the Fast Gas Phase Reaction between Ozones Nitric Oxide, Johnston et al.; J of Chem. Physics, Vol. 22, No. 4, 4/1954.

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